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NR/改性气相法白炭黑复合材料的性能研究
引用本文:周扬波,贾志欣,贾德民,古菊,王跃林,段先健. NR/改性气相法白炭黑复合材料的性能研究[J]. 橡胶工业, 2005, 52(11): 656-659
作者姓名:周扬波  贾志欣  贾德民  古菊  王跃林  段先健
作者单位:1. 华南理工大学,材料科学与工程学院,广东,广州,510641
2. 广州吉必时科技实业有限公司,广东,广州,510510
基金项目:国家自然科学基金资助项目(59933060)
摘    要:在改性气相法自炭黑填充NR胶料中加入粘合剂RH,研究粘合剂RH用量对胶料性能的影响,并与偶联剂Si69/气相法白炭黑胶料进行对比。结果表明,粘合剂RH的加入明显改善了硫化胶的物理性能,拉伸强度提高10%以上;粘合剂RH用量为4份时,硫化胶的综合物理性能最佳;有机改性剂M2改性气相法白炭黑参与了橡胶的共硫化,使硫化胶的交联密度增大;偶联剂Si69对硫化胶物理性能的改善效果不及粘合剂RH。

关 键 词:NR 改性气相法白炭黑 粘合剂 偶联剂 交联密度
文章编号:1000-890X(2005)11-0656-04
收稿时间:2005-05-21
修稿时间:2005-05-21

Properties of NR/modified fumed silica composite
ZHOU Yang-bo,JIA Zhi-xin,JIA De-min,GU Ju,WANG Yue-lin and DUAN Xian-jian. Properties of NR/modified fumed silica composite[J]. China Rubber Industry, 2005, 52(11): 656-659
Authors:ZHOU Yang-bo  JIA Zhi-xin  JIA De-min  GU Ju  WANG Yue-lin  DUAN Xian-jian
Affiliation:1. South China University of Technology,Guangzhou 510641,China;2. Guangzhou Jibishi Scientific and Technical Industry Co. Ltd, Guangzhou 510510,China
Abstract:The effect of the additional level of adhesive RH on the properties of NR/modified fumed silica compounds was investigated and these properties were compared to those of NR/Si69/silica compound. The results showed that the physical properties of vulcanizate improved significantly by adding adhesive RH,e. g. the tensile strength increased by above 10%;the vulcanizate with the best comprehensive physical properties was obtained by adding 4 phr adhesive RH;the fumed silica modified by the organic modifier M2 participated the covulcanization with NR to increase the crosslink density of vulcanizate;and the coupling agent Si69 was poorer than the adhesive RH for improving the physical properties of vulcanizate.
Keywords:NR   modified fumed silica   adhesive    coupling agent    crosslink density
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