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Experimental study of electrochemical corrosion behaviour of bilayer on AZ31B Mg alloy
Authors:Xinghua Guo  Maozhong An
Affiliation:aSchool of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, China;bState Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Science, Shenyang, China;cState Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin, China
Abstract:A bilayer on AZ31B magnesium alloy was prepared by first applying anodization to modify the substrate, and then depositing a self-assembled nanophase particle (SANP) film. Structure and corrosion behaviour are characterized by scanning electron microscopy, energy dispersion spectrometry, X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscope and electrochemical impedance spectroscopy. Experimental results indicate that the bilayer consists of a SNAP/loose layer and a dense layer, and provides the corrosion protection of Mg substrate for more than 354 h in 0.005 M NaCl solution. Therefore, the bilayer is effective to protect Mg alloy against corrosion for a long time.
Keywords:A  Mg  A  Organic coatings  B  EIS  C  Anodic films
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