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Preparation of polymeric biosurfactant containing sugar and fatty acid esters
Authors:Y Tokiwa  T Raku  M Kitagawa  R Kurane
Affiliation:(1) National Institute of Bioscience and Human-Technology, Higashi 1-1, Tsukuba, Ibaraki 305-8566, Japan e-mail: ytokiwa@nibh.go.jp Tel.: +81-298-61-6034 Fax: +81-298-56-4898, JP;(2) Konan Chemical Ind. Co. Ltd., Nakagawa 5-21, Takatsuki, Osaka 569-0066, Japan, JP;(3) Toyobo Research Center, Katata 2-1-1, Ohtsu, Shiga 520-0292, Japan, JP;(4) National Institute of Bioscience and Human-Technology, Higashi 1-1, Tsukuba, Ibaraki 305-8566, Japan, JP
Abstract: Vinyl sugar ester, 6-O-vinyladipoyl-d-glucose (VAG), was polymerized with vinyl fatty acid esters in dimethylformamide (DMF) with azobisisobutyronitrile (AIBN) to produce new amphiphilic polymers having branches of sugar and fatty acid esters. The influence of structural variations by changing the length of the alkyl chain of fatty acid moiety was examined by measurements of the surface tension and biodegradability. Received: 16 August 1999 / Accepted: 13 December 1999
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