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Electrocatalysts for bifunctional oxygen/air electrodes
Authors:V Nikolova  P Iliev  K Petrov  T Vitanov  E Zhecheva  R Stoyanova  I Valov  D Stoychev
Affiliation:1. Institute of Electrochemistry and Energy Systems, Bulgarian Academy of Sciences, Acad. G.Bonchev Street, bl.10., Sofia 1113, Bulgaria;2. Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, G. Bonchev Street, bl.11., Sofia 1113, Bulgaria;3. Institute of Physical Chemistry, Bulgarian Academy of Sciences, Acad. G.Bonchev Street, bl. 11, Sofia 1113, Bulgaria
Abstract:Oxygen reduction and evolution have been studied with respect to the development of bifunctional air/oxygen electrode (BFE). Three groups of catalysts have been prepared: (i) CuxCo3−xO4 by thermal decomposition of mixed nitrate and carbonate precursors; (ii) thin films of Co–Ni–Te–O and Co–Te–O were deposited by vacuum co-evaporation of Co, Ni and TeO2 and (iii) CoxOv/ZrO2 films were obtained by electrochemical deposition.
Keywords:Bifunctional air/oxygen electrode  Gas diffusion electrodes  Oxygen reduction and evolution  Electrocatalysts  Cobalt oxides
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