Dimethyl methyl phosphate: A new nonflammable electrolyte solvent for lithium-ion batteries |
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Authors: | JK Feng XJ SunXP Ai YL CaoHX Yang |
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Affiliation: | Department of Chemistry, Wuhan University, Wuhan 430072, China |
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Abstract: | A new fire retardant-dimethyl methyl phosphate (DMMP) was tested as a nonflammable electrolyte solvent for Li-ion batteries. It is found that in the addition of chloro-ethylene carbonate (Cl-EC) as an electrolyte additive, the electrochemical reduction of DMMP molecules can be completely suppressed and the graphite anode can be cycled very well with high initial columbic efficiency (∼84%) and excellent cycling stability in the DMMP electrolyte. The prismatic C/LiCoO2 batteries using 1.0 mol L−1 LiClO4 + 10% Cl-EC + DMMP electrolyte exhibited almost the same charge and discharge performances as those using conventional carbonate electrolytes, suggesting a feasible use of this new electrolyte for constructing nonflammable Li+-ion batteries. |
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Keywords: | Organic phosphate Electrolyte solvent Nonflammable electrolyte Lithium-ion batteries |
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