Quantitative analysis of oxygen-containing species adsorbed on the Pt surface of a polymer electrolyte fuel cell membrane electrode assembly electrode using stripping voltammetry

The quantity of oxygen-containing species adsorbed on Pt surface of a single-cell polymer electrolyte fuel cell membrane electrode assembly (PEFC MEA) in the gas-phase system was measured by stripping voltammetry (SV), of which the adsorbed amount is considered in terms of the quantity of electric charge required for stripping. The effect of different experimental parameters on the adsorption quantity was analyzed and an optimum condition for applying SV to a PEFC MEA electrode was then suggested. The electric charge required for stripping was observed to be linearly proportional to the potential and arose from 0.7 V vs. RHE. The adsorption amount of oxygen-containing species for the PEFC MEA at a cell temperature of 60 °C was 384 μC cm⁻²-Pt at a potential of 1.0 V vs. RHE. More importantly, considering the effect of O₂ partial pressure on the adsorption in the gas-phase PEFC MEAs, water is suggested to be the main source of the oxygen in adsorbed oxygen-containing species. The present method is well applicable to quantitative studies of the oxygen-containing species adsorbed on electrodes of PEFC MEAs.