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A cobalt polypyrrole composite catalyzed cathode for the direct borohydride fuel cell
Authors:H.Y. Qin  Z.X. LiuW.X. Yin  J.K. ZhuZ.P. Li
Affiliation:Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, PR China
Abstract:A cobalt polypyrrole carbon (Co-PPY-C) composite has been attempted for use as a cathode catalyst in a direct borohydride fuel cell (DBFC). A Co-PPY-C composite has been fabricated in laboratory and characterized by the field emission scanning electron microscopy, transmission electron microscopy, as well as X-ray photoemission spectroscopy. Fabricated Co-PPY-C catalyst demonstrates good short-term durability and activity which are comparable to those obtained from the Pt/C catalyst. A maximum power density of 65 mW cm−2 has been achieved at ambient conditions. This research concludes that metallo-organic coordination compounds would be potential candidates for use as cathode catalysts in the DBFC.
Keywords:Direct borohydride fuel cell   Cathode   Non-precious metal   Cobalt polypyrrole carbon   Cell performance
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