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Semi-analytical proton exchange membrane fuel cell modeling
Authors:Denver F. Cheddie  Norman D.H. Munroe
Affiliation:1. Department of Energy Studies, The University of Trinidad and Tobago, Pt. Lisas Campus, Esperanza Road, Brechin Castle, Couva, Trinidad and Tobago;2. Mechanical and Materials Engineering, CEAS 2103, Florida International University, 10555W Flagler Street, Miami, FL 33174, USA
Abstract:Mathematical techniques are presented which allow for analytical solutions of the catalyst layer transport and electrochemical problem in PEM fuel cells. These techniques transform the volumetric reaction terms to boundary flux terms, thereby eliminating the need for computational solving of the catalyst layer problem. The result is a semi-analytical fuel cell model—a computational model that entails analytical rather than computational catalyst layer solutions. This helps to alleviate the meshing difficulties inherent in the catalyst layers caused by large geometric aspect ratios, and hence reduce the computational requirements for fuel cell models.
Keywords:CL, catalyst layer   GDE, governing differential equation   GDL, gas diffusion layer   PEM, proton exchange membrane
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