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Reactive photonic film for label-free and selective sensing of cyanide
Authors:Li Xuesong  Peng Lihua  Cui Jiecheng  Li Weina  Lin Changxu  Xu Dan  Tian Tian  Zhang Guanxin  Zhang Deqing  Li Guangtao
Affiliation:Key Lab of Organic Optoelectronic and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China.
Abstract:Three-dimensional ordered inverse-opal films bearing a reactive trifluoroacetyl group are successfully constructed. Through the specific reaction between cyanide and trifluoroacetyl, the photonic films can selectively detect sub-micromolar levels of cyanide by distinct structural color change. Labeled molecules are not necessary for the sensing mechanism.
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