| 二烯丙基三硫的合成及稳定性试验 |
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| 引用本文： | 孙宏,张泽,杨颖,迟晓静,王伟华. 二烯丙基三硫的合成及稳定性试验[J]. 齐齐哈尔轻工业学院学报, 2012, 0(1): 40-42 |
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| 作者姓名： | 孙宏 张泽 杨颖 迟晓静 王伟华 |
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| 作者单位： | [1]齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔161006 [2]齐齐哈尔市环境监测中心站,黑龙江齐齐哈尔161005 |
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| 基金项目： | 黑龙江省教育厅面上项目计划（11551533） |
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| 摘 要： | 以硫代硫酸钠、烯丙基氯和硫化钠为原料，以四丁基溴化铵为相转移催化剂，铁氰化钾为催化剂，催化合成二烯丙基三硫。考察了2步反应催化剂的用量、反应时间对产率的影响。实验表明：铁氰化钾与烯丙基氯的重量为比1：1，反应时间4h，产率最高。O．02mg／mL可溶性淀粉和无水乙醚能使二烯丙基三硫稳定性提高。
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| 关 键 词： | 二烯丙基三硫 合成 稳定性 |
Synthesis of diallyl trisulfide and its stability |
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| SUN Hong,ZHANG Ze,YANG Ying,CHI Xiao-jing,WANG Wei-hua. Synthesis of diallyl trisulfide and its stability[J]. , 2012, 0(1): 40-42 |
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| Authors: | SUN Hong ZHANG Ze YANG Ying CHI Xiao-jing WANG Wei-hua |
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| Affiliation: | 1. Chemistry andChemicalEngineeringCollege, QiqiharUniversity, HeilongjiangQiqihar 161005, China; 2. Qiqihar Environment Monitoring Center, Heilongjiang Qiqihar 161005, China ) |
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| Abstract: | Allyl chloride, sodium thiosulfate and sodium sulfide were used to synthesize diallyl trisulfide by phase transfer catalyst tetrabutyl ammonium bromize and ferricyanatum kalium.When the weight ratio of allyl chloride and ferricyanatum kalium is 1：1, the reaction time is 4h, the yield is highest. The stability of diallyl trisulfide is increased in absolute ether and 0.02 mg/mL amidulin. |
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| Keywords: | diallyl trisulfide synthesis stability |
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