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FeMnMg氧化物Fenton催化降解有机废水
引用本文:贾若琨,李佳.FeMnMg氧化物Fenton催化降解有机废水[J].东北电力学院学报,2014(6):47-53.
作者姓名:贾若琨  李佳
作者单位:东北电力大学 化学工程学院,吉林 吉林,132012
基金项目:国家自然科学基金,吉林省科技发展计划项目
摘    要:采用高温煅烧硝化法制备Fe Mn Mg氧化物纳米晶,并采用扫描电镜(SEM)对Fe Mn Mg氧化物进行表征。结果表明,高温煅烧硝化法制备的Fe Mn Mg氧化物粒径为纳米范围,具有均匀的粒子尺寸和晶体尺寸。采用不同配比的Fe Mn Mg氧化物纳米晶催化剂对亚甲基蓝模拟的有机废水进行Fenton催化降解实验,对实验结果进行分析讨论。Fe Mn Mg的摩尔比为2∶3∶1的氧化物对亚甲基蓝的降解效果最好。当p H值为7左右,反应温度为25℃时,降解速率最快。Fe Mn Mg氧化物催化剂的投加量为0.012 g,保证了亚甲基蓝较好的降解率。在反应体系中采用选取30%H2O20.5 m L(即2 mmol/L),能达到较好的氧化降解效果。

关 键 词:Fe  Mn  Mg氧化物纳米晶  Fenton降解  亚甲基蓝

Research of FeMnMg Oxide Nano Particles Fenton-Degraded Methylene Blue
JIA Ruo-kun Ji,LI Jia.Research of FeMnMg Oxide Nano Particles Fenton-Degraded Methylene Blue[J].Journal of Northeast China Institute of Electric Power Engineering,2014(6):47-53.
Authors:JIA Ruo-kun Ji  LI Jia
Affiliation:( School of Chemical Engineering, Northeast Dianli University, Jilin Jilin 132012)
Abstract:Fe Mn Mg oxide nanocrystals were prepared by a high temperature calcination method,and they were characterized by scanning electron microscope( SEM). The results showed that Fe Mn Mg oxide nanocrystals prepared with temperature calcination method were nano particle size range,and the Fe Mn Mg oxide nanocrystals had uniform particle size and crystallite size. The strong H2O2- activating ability of Fe Mn Mg oxide nanocrystals showed promising applications in the oxidative degradation of organic pollutants methylene blue. Using the best catalyst of degradation effect of methylene blue in the experiments,carried on the optimal Fenton catalytic conditions on the exploring experiment. We studied the dosing quantity of catalyst Fe Mn Mg oxide nanocrystals,the addition content of H2O2,p H value and reaction temperature effect influence on catalytic degradation of methylene blue solution.
Keywords:FeMnMg oxide nanocrystals  Fenton reaction  Methylene blue
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