| 含氧化膦结构可溶性共聚芳酰胺的合成 |
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| 引用本文： | 张明,唐旭东,陈晓婷.含氧化膦结构可溶性共聚芳酰胺的合成[J].天津轻工业学院学报,2009(2):25-27. |
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| 作者姓名： | 张明 唐旭东 陈晓婷 |
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| 作者单位： | 天津科技大学材料科学与化学工程学院,天津300457 |
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| 摘 要： | 以双（对羧苯基）苯基氧化膦（BCPPO），对苯二甲酸（TPA）和4，4＇-二氨基二苯砜（DDS）为原料，通过Yamazaki膦酰化法合成聚芳酰胺．研究了反应温度、单体浓度、反应时间和溶剂体系对聚合物相对分子质量的影响，并用红外光谱对合成聚合物进行了结构表征，合成的聚芳酰胺可溶于N-甲基吡咯烷酮（NMP）、N，N-二甲基甲酰胺（DMF）、间甲酚等有机溶剂．
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| 关 键 词： | 聚芳酰胺 缩聚反应 BCPPO 溶解性 |
Synthesis of Soluble Aromatic Copolyamides Containing Phosphine Oxide Moiety |
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| ZHANG Ming,TANG Xu-dong,CHEN Xiao-ting.Synthesis of Soluble Aromatic Copolyamides Containing Phosphine Oxide Moiety[J].Journal of Tianjin University of Light Industry,2009(2):25-27. |
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| Authors: | ZHANG Ming TANG Xu-dong CHEN Xiao-ting |
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| Affiliation: | (College of Material Science and Chemical Engineering,Tianjin University of Science ＆ Technology Tianjin 300457 ,China) |
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| Abstract: | Aromatic polyamide was synthesized by the polycondensation of a bis （4-carboxyphenyl）phenyl phosphine oxide（BCPPO） ,terephthalic acid （TPA） with 4,4＇-Diaminodiphenylsulfone（DDS） by Yamazaki phosphorylation reaction. The effects of reaction temperature ,monomers concentration ,reaction time and solvent system on the molecular weight of the polymer were investigated. The structure of the phosphorus-containing polyamide copolymer was characterized by FTIR. The copolymer is readily soluble in a variety of organic solvents such as NMP,DMF,m-cresol and so on. |
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| Keywords: | aromatic polyamide polycondensation BCPPO solubility |
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