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紫外光固化水性聚氨酯-丙烯酸酯乳液性能的研究
引用本文:栾永红,李树材,龙丽娟,徐一飞. 紫外光固化水性聚氨酯-丙烯酸酯乳液性能的研究[J]. 天津轻工业学院学报, 2009, 0(3): 22-25
作者姓名:栾永红  李树材  龙丽娟  徐一飞
作者单位:天津科技大学材料科学与化学工程学院,天津300457
摘    要:选用异佛尔酮二异氰酸酯(IPDI)、聚酯二元醇、二羟甲基丙酸(DMPA)、甲基丙烯酸-β-羟乙酯(HEMA)等为原料,采用阴离子自乳化法制备了紫外光(UV)固化水性聚氨酯丙烯酸酯乳液考察了n(-NCO)/n(-OH)、DMPA及HEMA质量分数对乳液性能的影响结果表明,n(-NCO)n(-OH)为1.4-1.5,DMPA的质量分数为4.5%时乳液性能最好.同时,HEMA质量分数越高,乳液黏度越小.

关 键 词:紫外光固化  水性聚氨酯-丙烯酸酯  乳液  性能

Study on Performances of UV-Curable Waterborne Polyurethane-Acrylate Emulsion
LUAN Yong-hong,LI Shu-cai,LONG Li-juan,XU Yi-fei. Study on Performances of UV-Curable Waterborne Polyurethane-Acrylate Emulsion[J]. Journal of Tianjin University of Light Industry, 2009, 0(3): 22-25
Authors:LUAN Yong-hong  LI Shu-cai  LONG Li-juan  XU Yi-fei
Affiliation:(College of Material Science and Chemical Engineering,Tianjin University of Science & Technology,Tianjin 300457 ,China)
Abstract:The anionic polyester aqueous UV-curable polyurethane-acrylate was prepared by self-emulsifying process. It chooses raw materials such as isophorone diisocyanate (IPDI),polyethene glycol and dimethylol propinic acid(DMPA). Some influencing factors on the properties of waterborne polyurethane-acrylate emulsion have been fully studied, such as the mole ratio of--NCO/--OH,the mass fractions of DMPA and HEMA. The results show that when the mole ratio of--NCO/--OH is between 1.4 and 1.5,the mass fractions of DMPA is 4.5% ,the waterborne polyurethane-acrylate emulsion has the best properties. Meanwhile, the viscosity of the emulsion will become smaller with the increase of the mass fraction of HEMA.
Keywords:UV-curable  waterborne polyurethane-acrylate  emulsion  property
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