镀钨金刚石/铜复合材料的制备及导热性能(英文) |
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引用本文: | 戴书刚,李金旺,王昌机. 镀钨金刚石/铜复合材料的制备及导热性能(英文)[J]. 中国有色金属学会会刊, 2022, 32(9): 2979-2992. DOI: 10.1016/S1003-6326(22)65997-1 |
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作者姓名: | 戴书刚 李金旺 王昌机 |
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作者单位: | 1. 南京航空航天大学航天学院;2. 中国船舶重工集团第724研究所 |
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基金项目: | supported by the National Natural Science Foundation of China (No. 11802125); |
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摘 要: | 使用热扩散法在金刚石表面镀钨,并采用不同工艺参数制备镀钨金刚石/铜复合材料,观察不同样品的微观形貌,并使用激光闪射法测量样品的热导率,探索制备高热导率金刚石/铜复合材料的最佳工艺参数。研究结果表明,在金刚石表面镀钨可以改善界面结合,当镀覆时间为60 min时,镀层完整、均匀、平整,样品的热导率达到486 W/(m·K)。镀层的完整性和均匀性比镀层厚度更为重要。进一步对镀钨金刚石进行退火处理后,镀层与金刚石之间的冶金结合增强,制备得到的复合材料的热导率提高到559 W/(m·K)。
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关 键 词: | 金刚石/铜复合材料 镀层 热导率 界面结合 |
收稿时间: | 2021-08-11 |
Preparation and thermal conductivity of tungsten coated diamond/copper composites |
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Affiliation: | 1. College of Astronautics, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China;2. Inst. 724 of China Shipbuilding Industry Corporation, Nanjing 211153, China |
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Abstract: | Tungsten was plated on the surface of diamond by using thermal diffusion method. Different process parameters were employed to prepare the composites with tungsten, diamond and copper. The micro morphology of different samples was observed, and the thermal conductivity of samples was measured by laser flash method. The optimal process parameters for preparing diamond/copper composites with high thermal conductivity were investigated. The results indicated that plating tungsten on diamond could modify the interface bonding. When the diamond was plated for 60 min, the coating appeared intact, uniform and flat, and the thermal conductivity of the sample could reach as high as 486 W/(m·K). The integrity and uniformity were more important than thickness for the coating. When the tungsten-plated diamond was further annealed, the metallurgical bonding between the coating and the diamond was enhanced, and the thermal conductivity rose to 559 W/(m·K). |
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Keywords: | diamond/copper composites coating thermal conductivity interface bonding |
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