Esterification of Kraft lignin as a method to improve structural and mechanical properties of lignin‐polyethylene blends |
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Authors: | Laura Dehne Carlos Vila Bodo Saake Katrin U Schwarz |
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Affiliation: | 1. Department of Wood Science, Chemical Wood Technology, University of Hamburg, Hamburg, Germany;2. Thünen Institute of Wood Research, Hamburg, Germany;3. Chemical Engineering Department, University of Vigo, Faculty of Sciences, Ourense, Spain |
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Abstract: | Lignin is a promising candidate for blends with thermoplastic polymers. Still, this endeavour is a challenge due to poor compatibility between both components. In this article, the effect of lignin esterification on the improvement of the compatibility between hardwood Kraft lignin and high‐density polyethylene (PE‐HD) is investigated. For this purpose, lignin was esterified with acetic, propionic, and butyric anhydride; its amount in the blends varied from 10 to 40%. Light microscopic images of blends show a reduction in particle size and a more homogeneous distribution with increasing length of the ester carbon chains (C2 to C4). Modification of lignin enhances the moduli and strength characteristics of the blends. Butyrated lignin performs best, as tensile strength of blends can be retained near that of pure PE‐HD with up to 40% lignin content. An additional investigation of unmodified lignin with reduced particle size confirms that modification is the decisive factor to enhance blend properties; a sole reduction of particle size is insufficient. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44582. |
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Keywords: | blends biopolymers and renewable polymers compatibilization mechanical properties microscopy |
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