| 二茂铁衍生物的合成和表征 |
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| 引用本文： | 陈勇 刘惠英 等. 二茂铁衍生物的合成和表征[J]. 江苏石油化工学院学报, 2002, 14(2): 14-16 |
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| 作者姓名： | 陈勇 刘惠英 等 |
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| 作者单位： | 江苏石油化工学院化学工程系 江苏常州213016(陈勇，杨光，张新兵)，武汉大学化学系 湖北武汉430072(刘惠英) |
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| 基金项目： | 江苏石油化工学院科研基金资助 |
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| 摘 要： | 由二茂铁和芳胺作为原料通过芳基化作用合成了 3个新二茂铁衍生物。通过元素分析、IR、1 HNMR和MS确证了化合物结构。这些化合物的其它性质和用途还有待研究
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| 关 键 词： | 二茂铁衍生物 合成 表征 |
Synthesis and Characterization of Ferrocene Derivatives |
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| CHENG Yong ,YANG Guang ,ZHANG Xin-bing ,LIU Hui-ying. Synthesis and Characterization of Ferrocene Derivatives[J]. Journal of Jiangsu Institute of Petrochemical Technology, 2002, 14(2): 14-16 |
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| Authors: | CHENG Yong YANG Guang ZHANG Xin-bing LIU Hui-ying |
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| Affiliation: | CHENG Yong 1,YANG Guang 1,ZHANG Xin-bing 1,LIU Hui-ying 2 |
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| Abstract: | In the investigation,three new ferrocene derivatives were synthesized by arylation,using ferrocene and arylamines as the starting materials.The structures of these new derivatives were confirmed by elementary analysis,IR, 1HNMR and MS.The other properties and uses of these compounds are yet to be studied.The yields of three products were 17 3%,10 2% and 20 3%,respectively.The tests found that the key step is the preparation of diazotization of arylamine.The result showed that the appropriate reaction conditions should be:sulfuric acid as reaction medium;at room temperature. |
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| Keywords: | ferrocene derivative synthesis characterization |
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