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Cesium leaching from gamma-irradiated CsA and CsX zeolites
Authors:Lima Enrique  Ibarra Ilich A  Lara Victor  Bosch Pedro  Bulbulian Silvia
Affiliation:Universidad Autónoma Metropolitana, Iztapalapa, A. P. 55-532, Av. San Rafael Atlixco No. 186 Col. Vicentina, 09340 México, D.F., Mexico. lima@xanum.uam.mx
Abstract:The present study discusses the effect of γ-irradiation on Cs+-exchanged X and A zeolites. The incorporation of Cs+ ions into A and X zeolites was performed using three different cesium salts (chloride, nitrate or acetate). Cs+ ions immobilized into the vitrified zeolites by thermal treatment are located in different sites of the zeolite networks. It is found that γ-irradiation favors cesium retention depending on the cesium precursor salt used in the cationic exchange step.
Keywords:Zeolite   Cesium   Vitrification   Leaching   Gamma irradiation   Radionuclide   Nuclear waste
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