Application of various viscosity theories to the viscosity data of methyl methacrylate-acrylonitrile random copolymers |
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Authors: | AK Kashyap V Kalpagam |
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Affiliation: | Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore- 560012, India |
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Abstract: | Values of Ko, Flory constant related to unperturbed dimensions, are evaluated for methyl methacrylate-acrylonitrile random copolymers using Flory-Fox, Kurata-Stockmayer and Inagaki-Ptitsyn methods and compared with the Ko values obtained by Stockmayer-Fixman method. Ko values are seen to be less in solvents which have large a (Mark-Houwink exponent) values. A correlation between Ko and a is developed to arrive at a more reliable estimate of Ko for this copolymer system. |
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