| 自交联硅丙乳液聚合稳定性的研究 |
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| 引用本文： | 陈忠奎,范慧俐,康立训,郑延军.自交联硅丙乳液聚合稳定性的研究[J].化学建材,2004,20(6):5-7. |
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| 作者姓名： | 陈忠奎 范慧俐 康立训 郑延军 |
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| 作者单位： | 北京科技大学化学系 北京100083
(陈忠奎，范慧俐，康立训)，北京科技大学化学系 北京100083(郑延军) |
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| 摘 要： | 研究了以反应性乳化剂制备高硅含量自交联硅丙乳液的聚合工艺,结果表明:以反应性乳化剂代替普通乳化剂,采用后交联技术结合种子乳液法,分步控温,并加入丙二醇作为水解抑制剂,可以显著提高自交联硅丙乳液的聚合稳定性,获得高硅含量的自交联硅丙乳液。
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| 关 键 词： | 反应性乳化剂 自交联硅丙乳液 聚合稳定性 |
A Study of Polymerization Stability of Self-Crosslinked Silicone-Acrylate Emulsion |
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| Chen Zhong-kui et al // BeijingUniversity of Science & Technology.A Study of Polymerization Stability of Self-Crosslinked Silicone-Acrylate Emulsion[J].Chemical Materials for Construction,2004,20(6):5-7. |
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| Authors: | Chen Zhong-kui // BeijingUniversity of Science & Technology |
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| Affiliation: | Chen Zhong-kui et al // BeijingUniversity of Science & Technology |
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| Abstract: | Polymerization technology of self-crosslinked silicone-acrylate emulsion with high-organosilicone content pre-pared by reactive emulsifier was studied. Testing results showed that polymerization stability of self-crosslinked silicone-acrylate emulsion could be greatly improved and self-crosslinked silicone-acrylate emulsion with high organosiliconecontent could be prepared using reactive emulsifier in stead of ordinary emulsifier, by way of post-crosslinking technologycombined with seed emulsion polymerization, controlling temperature by steps and adding propylene glycol as hydrolyticdecomposition restrainer. |
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| Keywords: | reactive emulsifier self-crosslinked silicone-acrylate emulsion polymerization stability |
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