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Poly(styrene-co-divinylbenzene)-PAMAM-IDA chelating resin: Synthesis,characterization and application for Ni(II) removal in aqueous
引用本文:刘耀驰,;李学农,;王春志,;孔秀,;周荔子.Poly(styrene-co-divinylbenzene)-PAMAM-IDA chelating resin: Synthesis,characterization and application for Ni(II) removal in aqueous[J].中南工业大学学报(英文版),2014,21(9):3479-3484.
作者姓名:刘耀驰  ;李学农  ;王春志  ;孔秀  ;周荔子
作者单位:[1]College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China; [2]Baling Company, China Petroleum & Chemical Corporation, Yueyang 414000, China
基金项目:Foundation item: Project(51074192) supported by the National Natural Science Foundation of China
摘    要:PS-PAMAM-IDA chelating resins were prepared by low-generations of polyamidoamine(PAMAM) and then chloroacetic acid functionalizing commercially available ammoniated polystyrene matrix, to preconcentrate Ni2+ from synthetic aqueous samples. Different generations of PAMAM were used to obtain different chelating resins, PS-IDA, PS-1.0G PAMAM-IDA and PS-2.0G PAMAM-IDA. The synthesized resins were characterized by FTIR and elemental analysis. The effect of solution pH, kinetic studies, resin loading capacity, matrix effects etc., on metal ion adsorption to adsorbent phase, were studied by batch method. The PS-1.0G PAMAM-IDA resin was the most excellent adsorbents, with a maximum adsorption capacity of(24.09±1.79) mg/g for Ni2+ ion at pH=7. The interpretation of the equilibrium data was given by Langmuir isotherms model, and the correlation coefficient values for PS-IDA, PS-1.0G PAMAM-IDA and PS-2.0G PAMAM-IDA resins were 0.992, 0.994 and 0.987, respectively.

关 键 词:螯合树脂  聚苯乙烯  合成水样  二乙烯苯  Langmuir吸附  PAMAM  除水  应用

Poly(styrene-co-divinylbenzene)-PAMAM-IDA chelating resin: Synthesis,characterization and application for Ni(Ⅱ) removal in aqueous
LIU Yao-chi,LI Xue-nong,WANG Chun-zhi,KONG Xiu,ZHOUG Li-zi.Poly(styrene-co-divinylbenzene)-PAMAM-IDA chelating resin: Synthesis,characterization and application for Ni(Ⅱ) removal in aqueous[J].Journal of Central South University of Technology,2014,21(9):3479-3484.
Authors:LIU Yao-chi  LI Xue-nong  WANG Chun-zhi  KONG Xiu  ZHOUG Li-zi
Affiliation:1. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
2. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;Baling Company, China Petroleum & Chemical Corporation, Yueyang 414000, China
Abstract:chelating resin polyamidoamine iminodiacetic acid properties Ni(II)
Keywords:chelating resin  polyamidoamine  iminodiacetic acid  properties  Ni(Ⅱ)
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