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阴离子加聚对脉冲倒极电解合成聚合铝的影响
引用本文:皮科武,黄征青. 阴离子加聚对脉冲倒极电解合成聚合铝的影响[J]. 湖北工业大学学报, 2005, 20(4): 65-67
作者姓名:皮科武  黄征青
作者单位:湖北工业大学化学与环境工程学院,湖北,武汉,430068;湖北工业大学化学与环境工程学院,湖北,武汉,430068
摘    要:探索了实验过程中聚合SiO3^2-和SO4^2-离子团的加入对脉冲自动倒极电解合成聚合氯化硅酸硫酸铝、聚合氯化硅酸铝、聚合氯化硫酸铝和聚合氯化铝产品稳定性的影响,确定了最佳的合成条件.然后采用酸解、碱聚和陈化镜检,对产品的稳定性进行了研究.结果表明:聚合SiO3^2-与SO4^2-离子对聚合铝凝剂稳定性的影响大小顺序为:SiO3^2-+SO4^2->SO4^2->SiO3^2-.

关 键 词:铝基絮凝剂  脉冲倒极电解  酸解  碱聚
文章编号:1003-4684(2005)08-0065-03
收稿时间:2004-12-31
修稿时间:2004-12-31

Research on the Effect of Synthesis of Al-based Coagulants by Pulse Auto-rearrange able Electrodes Electrolysis through Adding Poly SiO2-3 and SiO2-3 Ions
PI Ke-wu,HUANG Zheng-qing. Research on the Effect of Synthesis of Al-based Coagulants by Pulse Auto-rearrange able Electrodes Electrolysis through Adding Poly SiO2-3 and SiO2-3 Ions[J]. Journal of Hubei University of Technology, 2005, 20(4): 65-67
Authors:PI Ke-wu  HUANG Zheng-qing
Abstract:The impact of poly SiO~(2-)_3 and SO~(2-)_4 ions on the stability of Al-based coagulants produced by Pulse Auto-rearrange able Electrodes Electrolysis was investigated in this paper. Al-based coagulants includes poly-aluminum silicate sulfate chloride (PASSC), poly-aluminum silicate chloride (PASiC), poly-aluminum sulfate chloride (PASC) and poly-aluminum chloride (PAC).Their stability was studied by acid addition, base addition and long time aging ,which shows that the impact of poly SiO~(2-)_3 and SO~(2-)_4 ions on the stability of Al-based coagulants is poly SiO~(2-)_3 and SO~(2-)_4>SO~(2-)_4>poly SiO~(2-)_3.
Keywords:Al-based goagulants   pulse auto-rearrange able electrodes electrolysis   acid addition   base addition
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