An ambipolar polymer additive for enhanced open circuit voltage in a bulk heterojunction solar cells

Open circuit voltage (V_OC) of organic bulk heterojunction solar cell is extended by the addition of a 20 wt % of F8TBT, an ambipolar polymer in the active layer matrixes (P3HT:PCBM) and then spin casted (1000 rpm/30 s) in the optimized devices on the PEDOT:PSS layer of the ITO glass. A substantial increase in the open circuit voltage from approximately 0.61–0.88 V (44.26%) has been observed with slight increase in efficiency up to 1.91% in the fabricated devices. However, further increment of F8TBT content to 40 wt % reduces the photovoltaic efficiency and affects the J_SC values remarkably, possibly due the excess amount of resistance developed. The enhancement of V_OC is attributed to the ambipolar nature of F8TBT polymer which facilitates the generated electron and hole transfer at the respective electrodes, enhanced π–π* conjugation in polymer matrix, a superior nanoscale separation, and better molecular conformation at the film interface, thus giving an ample opportunities to explore the impact of blending of materials rather than depositing a thin buffer layer by expensive vapor phase technologies. The details of electrical and microstructure characterization of the film were analyzed by AFM, SEM, UV–Vis, J–V characteristics, and EQE techniques. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43042.