| 球碳衍生物在钕系催化剂催化丁二烯聚合中的应用——催化剂的相态 |
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| 引用本文： | 郭守堂,陈滇宝.球碳衍生物在钕系催化剂催化丁二烯聚合中的应用——催化剂的相态[J].弹性体,1996,6(1):12-16. |
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| 作者姓名： | 郭守堂 陈滇宝 |
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| 作者单位： | 青岛化工学院高材系 |
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| 摘 要： | 在Ｎｄ（ｎａｐｈ）３－Ａｌ（ｉ－Ｂ３）３－Ａｌ（ｉ－Ｂｕ）２Ｃｌ（简称Ｎｄ—Ａｌ－Ｃｌ）三元催化体系中加入球碳衍生物Ｃ６０Ｘｎ（Ｘ为某卤素基因），改善了催化剂的相态稳定性，同时对比考察了几种溶剂对Ｃ６０Ｘｎ的溶解性，发现溶解度都比加氢汽油好，以其催化丁二烯聚合，活性也有所提高。
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| 关 键 词： | 钕系催化剂，相态，球碳衍生物 |
APPLICATION OF C60X. IN BUTADIENEPOLYMERIZATION WITH NEODYNIUM CATALYST-PHASE STATE OF CATALYST |
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| Guo Shouxue,Chen dianbao, Zhong Chongqi,Tang Xueming..APPLICATION OF C60X. IN BUTADIENEPOLYMERIZATION WITH NEODYNIUM CATALYST-PHASE STATE OF CATALYST[J].China Elastomerics,1996,6(1):12-16. |
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| Authors: | Guo Shouxue Chen dianbao Zhong Chongqi Tang Xueming |
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| Abstract: | Phase stability of Nd(naph),-Al(i-Bu)3 - Al(i - Bu)2Cl(abbre.Nd - Al - CI)trinary catalyst system was improved by adding C6oXn Solubility and catalysing activity of C6oXn in severalsolutes (CH2Cl2 and tolene)were compared.Results showed that their solubility was higher thanthat in hydrogenated gasoline.When being used to catalyst butadiene polymerization,the activityincreased |
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| Keywords: | Neodynium catalyst system Phase state C_60X_n |
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