| 聚丙烯酸酯无皂核壳乳液聚合反应的研究 |
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| 引用本文： | 张瑜,韦亚兵,熊家文.聚丙烯酸酯无皂核壳乳液聚合反应的研究[J].化学与粘合,2002(3):112-114. |
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| 作者姓名： | 张瑜 韦亚兵 熊家文 |
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| 作者单位： | 南京化工大学材料学院 江苏南京210009
(张瑜，韦亚兵)，南京化工大学材料学院 江苏南京210009(熊家文) |
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| 摘 要： | 采用无乳液聚合技术，合成了PBA／PMMA核壳结构的复合乳液，研究齐聚物用量及配比、温度，DDM对齐聚物聚合反应速率的影响，以及引发剂浓度，齐聚物浓度等因素对核壳乳液聚合速率的影响。
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| 关 键 词： | 无皂核壳 乳液聚合 核壳结构 |
| 文章编号： | 1001-0017(2002)03-0112-03 |
| 修稿时间： | 2001年7月26日 |
The Acrylate Soapless Emulsion Polymerization with Core- Shell Structure |
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| ZHANG Yu,WEI Ya-bing and XIONG Jia-wen.The Acrylate Soapless Emulsion Polymerization with Core- Shell Structure[J].Chemistry and Adhesion,2002(3):112-114. |
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| Authors: | ZHANG Yu WEI Ya-bing and XIONG Jia-wen |
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| Abstract: | A composite emulsion was made by seeded soapless emulsion polymerization,in which the poly(n-butyl acrylate)(Pn-BA)is the core and the poly(methyl methacrylate)(PMMA)is the shell.The effect of oligomer ratio,temperature,DDM etc. on the oligomer polymerization reaction rate,and the effect of the concentration of initiator,the amount of oligomer etc. on the core-shell polymerization were studied. |
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| Keywords: | soapless emulsion polymerzation core-shell structure |
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