| 钴锌合金在氯化胆碱-尿素离子液体中的电沉积行为 |
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| 引用本文： | 王小娟,李慧,王娇,付雄之,顾建胜.钴锌合金在氯化胆碱-尿素离子液体中的电沉积行为[J].材料保护,2010,43(3). |
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| 作者姓名： | 王小娟 李慧 王娇 付雄之 顾建胜 |
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| 作者单位： | 苏州大学材料与化学化工学部,江苏,苏州,215123;苏州大学材料与化学化工学部,江苏,苏州,215123;苏州大学材料与化学化工学部,江苏,苏州,215123;苏州大学材料与化学化工学部,江苏,苏州,215123;苏州大学材料与化学化工学部,江苏,苏州,215123 |
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| 摘 要： | 为探索新型的Co-Zn合金电镀工艺,在氯化胆碱-尿素离子液体中电沉积了钴锌合金镀层,探讨了阴极电位、Co(Ⅱ)/Zn(Ⅱ)浓度比、温度及时间等工艺参数对电沉积的影响,并对合金镀层性能进行了测试.结果表明:在氯化胆碱-尿素离子液体中,控制体系的组成和沉积条件,可得到表面均匀、附着力强、有金属光泽的非晶态Co-Zn合金镀层,其中Co的质量分数可达90%.
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| 关 键 词： | 氯化胆碱-尿素离子液体 电沉积 钴锌合金 非晶态 |
Electrodeposition of Co-Zn Alloy in Choline Chloride-Urea Ionic Liquid |
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| WANG Xiao-juan,LI Hui,WANG Jiao,FU Xiong-zhi,GU Jian-sheng.Electrodeposition of Co-Zn Alloy in Choline Chloride-Urea Ionic Liquid[J].Journal of Materials Protection,2010,43(3). |
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| Authors: | WANG Xiao-juan LI Hui WANG Jiao FU Xiong-zhi GU Jian-sheng |
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| Affiliation: | WANG Xiao-juan,LI Hui,WANG Jiao,FU Xiong-zhi,GU Jian-sheng(College of Chemistry,Chemical Engineering , Materi-als Science,Suzhou University,Suzhou 215123,China). |
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| Abstract: | Co-Zn alloy coating was prepared via electrodeposition in choline chloride- urea ionic liquid. The effects of cathode potential, concentration ratio of Co(Ⅱ)- to Zn(Ⅱ), temperature and deposition time on the elec-tredeposition behavior were investigated, and the properties of the alloy coating were also analyzed. Results indicate that uniform amorphous Co-Zn alloy coating with metallic luster and good ad-hesion to substrate can be readily obtained by properly adjusting the composition of the choline chloride-urea ionic liquid and elec-trodeposition parameters as well, and the Co content can reach 90% ( mass fraction). |
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| Keywords: | choline chloride-urea ionic liquid electrodeposition Co-Zn alloy amorphous |
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