负载型氧化铜烟气脱硫剂NH_3再生研究 |
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引用本文: | 杨 勇,钱运华,王 俊,蒋金龙,石荧荧,方慧敏.负载型氧化铜烟气脱硫剂NH_3再生研究[J].淮阴工学院学报,2014(1):1-4. |
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作者姓名: | 杨 勇 钱运华 王 俊 蒋金龙 石荧荧 方慧敏 |
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作者单位: | [1]淮阴工学院生命科学与化学工程学院,江苏淮安223003; [2]江苏省凹土资源利用重点实验室,江苏淮安223003 |
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基金项目: | 江苏省科技支撑(工业)计划项目(BE2008088);江苏省环保厅基金项目(2013031) |
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摘 要: | 以NH3为还原性气体对负载型CuO/复合载体脱硫剂进行了再生研究。在固定床反应器中对再生脱硫剂的脱硫性能进行了考察,以穿透时间为指标,结合BET和FT-IR表征手段,考察了温度、时间对脱硫剂再生性能的影响。实验结果表明:最佳再生温度和时间分别为300℃、100min;脱硫剂CuO/活性炭+凹土吸附试具有丰富的孔结构;脱硫剂重复使用4次,仍然保持了较好的脱硫性能,其穿透硫容高于30mg/g。
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关 键 词: | 凹土 活性炭 CuO 脱硫剂 再生 |
NH3 Regeneration of Supported CuO for Flue Gas Desulfurization |
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Affiliation: | YANG Yong, QIAN Yun-hua, WANG Jun, JIANG Jin-long, SHI Ying-ying, FANG Hui-min ( 1. Faculty of Life Science & Chemical Engineering, Huaiyin Institute of Technology, Huaian Jiangsu 223003, China ; |
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Abstract: | The regeneration of absorbent CuO supported on the complex carrier of attapulgite and activated car -bon was carried out using NH 3 for the flue gas desulfurization .With the breakthrough time as an index , the des-ulfurization performance of regenerated sorbents under different conditions was tested in a fixed -bed reactor , combined with characterizations of BET and FT -IR.The experimental results showed that the optimum regen-eration time and regeneration temperature was 300℃and 100 min, respectively.Due to the porous structure of CuO/complex carrier , the breakthrough sulfur capacity of the sorbent regenerated for 3 times was still over 30 mg/g, which proved its good future in industrial application . |
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Keywords: | attapulgite activated carbon CuO desulfurizer regeneration |
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