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基于氧化石墨烯功能材料提高PEDOT:PSS电极性研究
引用本文:郭阳阳,王文军,李淑红,刘云龙,刘婷婷,赵玲,王青如,高学喜.基于氧化石墨烯功能材料提高PEDOT:PSS电极性研究[J].光电子.激光,2019,30(7):697-703.
作者姓名:郭阳阳  王文军  李淑红  刘云龙  刘婷婷  赵玲  王青如  高学喜
作者单位:聊城大学物理科学与信息工程学院,山东 聊城,252059;山东省光通信科学与技术重点实验室,山东 聊城,252059
基金项目:国家自然科学基金(61775089)、山东省重点实验室产业联盟基金(SDKL2016038)和山东省自然科学基金(ZR2017BF009)资助项目 (1.聊城大学 物理科学与信息工程学院,山东 聊城 252059; 2.山东省光通信科学与技术重点实验室,山东 聊城 252059)
摘    要:基于聚(3,4-乙烯二氧噻吩)-聚苯乙烯磺酸(PE DOT:PSS)/氧化石墨烯(GO)混合溶液,利用旋涂法制 备了高电导率透明阳极,并采用硫酸(H2SO4)浸渍处理的方式,使其导电特性进一步 增强。采用最佳方式 处理的PEDOT:PSS/GO混合薄膜在厚度为40 nm时,其方阻为80 Ω/□,在550 nm时的透过率达到87.7%。 基于表面形貌的AFM图,吸收光谱和拉曼光谱,在少量氧化石墨烯掺杂和硫酸处理后,PSS -和PEDOT+链 相分离,使得PEDOT:PSS的结构发生了变化,提高了混合薄膜的电导率。与ITO和纯PEDOT: PSS分 别作为阳极的OLED器件相比,采用优化的PEDOT:PSS/GO混合薄膜作为阳极时的OLED器件具有 最低 的启亮电压和最高的电流效率,其最大亮度是纯PEDOT:PSS作为阳极的OLED的1.7倍。较高 的透过率, 电导率和HOMO能级,尤其是表面形貌的改变都有利于PEDOT:PSS/GO阳极OLED器件性能的改善 。

关 键 词:柔性OLED  氧化石墨烯功能材料  PEDOT:PSS/GO混合薄膜  混合阳极  电流效率
收稿时间:2018/12/21 0:00:00

Improved property of PEDOT:PSS anode using graphene oxide function material
GUO Yang-yang,WANG Wen-jun,LI Shu-hong,LIU Yun-long,LIU Ting-ting,ZHAO Ling,WANG Qing-ru and GAO Xue-xi.Improved property of PEDOT:PSS anode using graphene oxide function material[J].Journal of Optoelectronics·laser,2019,30(7):697-703.
Authors:GUO Yang-yang  WANG Wen-jun  LI Shu-hong  LIU Yun-long  LIU Ting-ting  ZHAO Ling  WANG Qing-ru and GAO Xue-xi
Affiliation:1.School of Physical Science and Information Technology,Liaocheng Unive rsity,Shandong 252059,China; 2.Shandong Provincial Key Laboratory of Optical Communication Science an d Technology,Shandong 252059,1.School of Physical Science and Information Technology,Liaocheng Unive rsity,Shandong 252059,China; 2.Shandong Provincial Key Laboratory of Optical Communication Science an d Technology,Shandong 252059,1.School of Physical Science and Information Technology,Liaocheng Unive rsity,Shandong 252059,China; 2.Shandong Provincial Key Laboratory of Optical Communication Science an d Technology,Shandong 252059,1.School of Physical Science and Information Technology,Liaocheng Unive rsity,Shandong 252059,China; 2.Shandong Provincial Key Laboratory of Optical Communication Science an d Technology,Shandong 252059,1.School of Physical Science and Information Technology,Liaocheng Unive rsity,Shandong 252059,China; 2.Shandong Provincial Key Laboratory of Optical Communication Science an d Technology,Shandong 252059,1.School of Physical Science and Information Technology,Liaocheng Unive rsity,Shandong 252059,China; 2.Shandong Provincial Key Laboratory of Optical Communication Science an d Technology,Shandong 252059,1.School of Physical Science and Information Technology,Liaocheng Unive rsity,Shandong 252059,China; 2.Shandong Provincial Key Laboratory of Optical Communication Science an d Technology,Shandong 252059 and 1.School of Physical Science and Information Technology,Liaocheng Unive rsity,Shandong 252059,China; 2.Shandong Provincial Key Laboratory of Optical Communication Science an d Technology,Shandong 252059
Abstract:
Keywords:flexible organic light emitting diodes  graphene oxide function mater ial  PEDOT:PSS/GO hybrid films  hybrid anode  current efficiency of OLEDs
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