| 偶氮染料的偶氮-醌腙互变异构的研究(Ⅰ) 1-苯基偶氮萘的偶氮-醌腙异构 |
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| 引用本文： | 田雅珍,吴祖望.偶氮染料的偶氮-醌腙互变异构的研究(Ⅰ) 1-苯基偶氮萘的偶氮-醌腙异构[J].化工学报,1995,46(2):152-157. |
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| 作者姓名： | 田雅珍 吴祖望 |
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| 作者单位： | 大连理工大学化工学院,大连理工大学化工学院,大连理工大学化工学院,大连理工大学化工学院 大连116012,大连116012,大连116012,大连116012 |
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| 摘 要： | 本文合成了10个1-苯基偶氮萘染料,并测定了其~1H、~（13）C NMR（核磁共振）谱,对~1H谱进行了归属,确定了2种异构体的判据,讨论了萘环上取代基的电子效应和空间障碍、溶剂的极性和pH值对偶氮-醌腙互变异构的影响。
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| 关 键 词： | 苯基 偶氮 偶氮体 醌腙体 染料 偶氮染料 |
AZO-HYDRAZONE TAUTOMERISM OF 1-PHEN YLAZONAPHTHALENE DERIVATIVES |
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| Tian Yazhen,Wu Zuwang,Zhang Shufeng and Wang Guijuan.AZO-HYDRAZONE TAUTOMERISM OF 1-PHEN YLAZONAPHTHALENE DERIVATIVES[J].Journal of Chemical Industry and Engineering(China),1995,46(2):152-157. |
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| Authors: | Tian Yazhen Wu Zuwang Zhang Shufeng and Wang Guijuan |
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| Affiliation: | Tian Yazhen,Wu Zuwang,Zhang Shufeng and Wang Guijuan(College of Chemical Engineering,Dalian University of Technology,Dalian ) |
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| Abstract: | Ten 1 - phenylazonaphthalene dyes were synthesized, and their 1H,13C NMR spectra were recorded with emphasis on the criteria of azo and hydrazone tautomers on 1H,13 C NMR spectra. The electron effect and stereohindrance of substituents on the naphthalene ring, as well as the solvent effect on azo - hydrazone tautomerism were discussed. |
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