Electrical-percolation effects in epoxy resin/ion-exchange resin/polyaniline anticorrosion composite materials |
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Authors: | N. N. Petrov I. V. Falina T. V. Koval’ R. V. Gorokhov N. V. Shel’deshov N. N. Bukov |
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Affiliation: | 1.OOO Intellektual’nye Kompositsionnye Resheniya,Krasnodar,Russia;2.Kuban State University,Krasnodar,Russia |
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Abstract: | A new type of epoxy–polyelectrolyte anticorrosion protective material based on epoxy resin, ion-exchange resin, and polyaniline has been studied. Electrical-percolation transitions are observed after submerging stainless-steel plates coated with epoxy–polyelectrolyte compositions in a solution of NaCl. Conductivity data processed within a percolation model show that the modification of ion-exchange resin by polyaniline strongly influences the coating model parameters owing to changes in physicochemical and morphological properties of ion-exchange resin. It is established that the electrochemical response to the action of an aqueous salt solution can be controlled by variation of the material composition. |
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