| N,N'-二苯基-N,N'-二(2-菲基)-4,4'-联苯二胺的合成及结构表征 |
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| 引用本文： | 周袭非,魏冰,王勇,王伟.N,N'-二苯基-N,N'-二(2-菲基)-4,4'-联苯二胺的合成及结构表征[J].化工新型材料,2007,35(9):48-49. |
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| 作者姓名： | 周袭非 魏冰 王勇 王伟 |
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| 作者单位： | 辽宁科技大学化工学院,鞍山,114051;大连理工大学化工学院,大连,116023 |
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| 摘 要： | 以二苯胺和菲为初始原料,合成了空穴传输层材料N,N'-二苯基-N,N'-二(2-菲基)-4,4'-联苯二胺.并用红外光谱、核磁共振谱、元素分析对其结构进行了表征.对反应的工艺条件进行了优化,优化反应条件为邻二氯苯为反应体系的较佳溶剂,相转移催化剂TBAB的质量分数为4.5%.
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| 关 键 词： | 二苯胺 菲 空穴传榆层材料 合成 表征 |
| 修稿时间： | 2007年4月3日 |
Synthesis and characterization of N,N'-diphenyl-N,N'-di(2-phenanthryl)-4,4'-benzidine |
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| Zhou Xifei,Wei Bing,Wang Yong,Wang Wei.Synthesis and characterization of N,N'-diphenyl-N,N'-di(2-phenanthryl)-4,4'-benzidine[J].New Chemical Materials,2007,35(9):48-49. |
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| Authors: | Zhou Xifei Wei Bing Wang Yong Wang Wei |
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| Abstract: | Hole-transmission material N,N'-diphenyl-N,N'-di(2-phenanthryl)-4,4'-benzidine was synthesized from diphnylamine and phenanthrene.The structures were characberized by IR'1HNMR and elemental analysis.The factors of affecting reaction were studied.The reaction parameters were optimized as follows:o-dichlorobenzene as solvent phase transfer catalyst TAAB was 4.5%.Under these conditions the yield was up to 68.9%. |
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| Keywords: | diphnylamine phenanthrene hole-transmission material synthesis characterization |
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