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Possibility of Superconductivity of the 2212 Phase in the Bi(Pb)-Sr-Ce-Cu-O System
Authors:Hiroyuki Sasakura  Yoshiya Akagi  Shigeki Tsukui  Takashi Oka  Motoaki Adachi
Affiliation:(1) Department of Physics, Hamamatsu University School of Medicine, 1-20-1 Handayama, 431-3192 Hamamatsu Shizuoka, Japan;(2) Research Institute for Advanced Science and Technology, Osaka Prefecture University, 599-8570 Sakai, Osaka, Japan
Abstract:Synthesis of the Bi-2212 compound in the Bi-Sr-Ce-Cu-O system has been already known. But, there has been no report on superconductivity of the compound yet. We have prepared many Bi-2212 samples partially substituted by Pb for Bi in the Bi-Sr-Ce-Cu-O system. The nominal composition is (Bi2−y Pb y )Sr2(Sr1−x Ce x )Cu2O z . Then, we have investigated possibility of superconductivity for the samples. As a result, we find that a sample with nominal composition ofx=0.23 andy=0.1, which is of almost the single 2212 phase, shows an anomaly at about 70 K in addition to temperature dependence of the resistivity like a semiconductor. Furthermore, the sample also shows a decrease of magnetic susceptibility starting at about 70 K with decreasing temperature. These experimental results can be considered to result from superconductivity of the 2212 phase in the Bi(Pb)-Sr-Ce-Cu-O system.
Keywords:Bi (Pb)-Sr-Ce-Cu-O system  Bi-2212 phase  superconductivity
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