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Characterization of multi-scale synergistic toughened nanostructured YSZ thermal barrier coatings: From feedstocks to coatings
Affiliation:1. Department of Materials Science, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, PR China;2. National Engineering Laboratory for Modern Materials Surface Engineering Technology&The Key Lab of Guangdong for Modern Surface Engineering Technology, Guangdong Institute of New Materials, Guangzhou 510651, PR China;3. Key Laboratory of Inorganic Coating Materials CAS, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, PR China;1. Hebei University of Technology, 300130, Tianjin, China;2. National Key Laboratory for Remanufacturing, Academy of Armored Forces Engineering, 100072, Beijing, China;1. Department of Materials Science, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, PR China;2. Key Laboratory of Inorganic Coating Materials CAS, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, PR China;3. School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, PR China
Abstract:The nanostructured 8YSZ thermal barrier coatings were deposited by atmospheric plasma spraying onto K417 G nickel-based superalloy with high velocity oxygen fuel sprayed NiCoCrAlYCe bond-coat using as-prepared nanostructured t´-Zr0.9Y0.1O1.95 feedstocks for the first time. The microstructure and mechanical properties of nanostructured and conventional 8YSZ coatings were comparatively investigated systematically. The results revealed that both coatings were composed of t´-Zr0.9Y0.1O1.95 phase and the formation mechanism of t´ phase was elucidated. The nanostructured 8YSZ coatings demonstrated typical bi-modal microstructure, whereas the conventional 8YSZ coatings exhibited mono-modal microstructure. Furthermore, the bi-modal microstructure of nanostructured 8YSZ coatings was analysed by elastic modulus and nanohardness Weibull distribution plots. The high and low slopes in Weibull distribution plots corresponded to unmelted and melted regions of nanostructured 8YSZ coatings, respectively. The fracture toughness and bonding strength of nanostructured coatings were higher than that of conventional 8YSZ coatings. Finally the reasons were explained in detail.
Keywords:Nanostructured 8YSZ  Bi-modal microstructure  Mechanical properties  Plasma spraying  Thermal barrier coatings
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