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Cellular ceramics by slip casting of emulsified suspensions
Affiliation:1. CIRIMAT, CNRS-INP-UPS, Université Toulouse 3 Paul-Sabatier, 118 route de Narbonne, F-31062, Toulouse Cedex 9, France;2. Plateforme Nationale CNRS de Frittage Flash, PNF², MHT, Université Toulouse 3 - Paul-Sabatier, 118 route de Narbonne, F-31062, Toulouse Cedex 9, France;3. CIRIMAT, CNRS-INP-UPS, INP-ENSIACET, 4 allée Emile Monso, BP 44362, F-31030, Toulouse Cedex 4, France;1. CEITEC IPM, Institute of Physics of Materials, Czech Academy of Sciences, Zizkova 22, 616 00 Brno, Czech Republic;2. CEITEC BUT, Brno University of Technology, Purkynova 123, 612 00 Brno, Czech Republic;3. Institute of Physics of Materials, Czech Academy of Sciences, Zizkova 22, 616 00 Brno, Czech Republic;4. Institute of Materials Science and Engineering, Brno University of Technology, Technicka 2, 616 00 Brno, Czech Republic;1. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;2. School of Materials Science and Engineering, The University of New South Wales, Sydney 2052, Australia
Abstract:Cellular ceramics were processed by slip casting of alumina suspensions emulsified with sunflower oil. A model behavior was derived on assuming that the templating dispersed phase and its droplet size distribution are retained as porosity in the resulting cellular ceramics, whereas the continuous ceramic suspension evolves to dense struts and thin inter-pore walls. Representative values of solid load and oil to suspension ratio were selected to seek close packed spatial distribution of nearly spherical. Stirring rate and additions of surfactant were also varied for greater flexibility in adjusting droplet size and rheology of the corresponding emulsified suspensions; this also contributes to minimize undue losses of porosity, relative to the model behavior, and determines microstructural features such as size distributions and average cell size.
Keywords:Cellular ceramics  Slip casting  Emulsification  Colloidal processing
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