| 无溶剂微波法合成meso-苯基四苯井卟啉锌 |
| |
| 引用本文： | 谭迪 杨克儿 佟珊玲 阎雁. 无溶剂微波法合成meso-苯基四苯井卟啉锌[J]. 化学与生物工程, 2006, 23(7): 51-53 |
| |
| 作者姓名： | 谭迪 杨克儿 佟珊玲 阎雁 |
| |
| 作者单位： | 汕头大学化学系,广东汕头515063 |
| |
| 摘 要： | 采用无溶剂微波固相法，合成了meso-苯基四苯并卟啉锌（Zn-PnTBP，n=1，2，3，4），通过紫外一可见光谱表征了其结构。结果表明原料配比、研磨时间、微波辐射时间等对反应的主要产物和产率都有很大影响，最终确定了形成Zn-P。TBP的最佳条件：n（邻苯二甲酰亚铵）：n（苯乙酸）：n（乙酸锌）=1．0：1．4：0．8、研磨时间为5min，在中等微波辐射下反应13min，产率达到28％。
|
| 关 键 词： | 苯基四苯并卟啉锌 研磨 微波辐射 |
| 文章编号： | 1672-5425（2006）07-0051-03 |
| 收稿时间： | 2006-05-08 |
| 修稿时间： | 2006-05-08 |
Synthesis of meso-Phenyl Substituted Tetrabenzoporphyrinato-Zinc by Microwave Irradiation under Solvent Free Condition |
| |
| TAN Di, YANG Ke-er, TONG Shah-ling, YAN Yah. Synthesis of meso-Phenyl Substituted Tetrabenzoporphyrinato-Zinc by Microwave Irradiation under Solvent Free Condition[J]. Chemistry & Bioengineering, 2006, 23(7): 51-53 |
| |
| Authors: | TAN Di YANG Ke-er TONG Shah-ling YAN Yah |
| |
| Abstract: | meso-Phenyl substituted tetrabenzoporphyrinato-zinc(Zn-P_nTBP) were prepared by microwave irradiating on the reactant mixture of phthalimide,phenylacetic acid and zinc acetate.The products were characterized by UV-Vis determination.Experimental results indicated that the ratio of reactants,grinding time and microwave irradiation time had great influence on the main product and its yield.The optimum conditions for Zn-P_nTBP were determined in the end. |
| |
| Keywords: | meso-phenyl substituted tetrabenzoporphyrinato-zinc grinding microwave irradiation |
| 本文献已被 CNKI 维普 等数据库收录！ |
