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Influence of La2O3 addition on microstructure and wear resistance of Fe-Cr-C cladding formed by arc surface welding
Authors:ZHOU Yefei  YANG Yulin  QI Xiaowen  JIANG Yongwen  YANG Jian  REN Xuejun  YANG Qingxiang
Affiliation:1 (1. State Key Laboratory of Metastable Materials Science & Technology, Yanshan University, Qinhuangdao 066004, China; 2. School of Engineering, Liverpool John Moores University, Liverpool L3 3AF, UK)
Abstract:The Fe-Cr-C claddings formed by arc surface welding with different La2O3 additions were investigated. The microstructures were observed by optical microscopy (OM), field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). The phase structures were measured by X-ray diffraction (XRD). The wear resistances of the claddings were tested by friction and wear experiment. On this basis, the carbide refinement mechanism by inclusion enriched with La was discussed theoretically. The results showed that, the microstructure of the Fe-Cr-C cladding consisted of primary (Cr,Fe)7C3 carbides and eutectic (γ-Fe+(Cr,Fe)7C3 ) structure. With La2O3 addition increasing, the primary carbides were refined, and the mass loss of the cladding decreased gradually. The Fe-Cr-C cladding with 4wt.% La2O3 addition had a best wear resistance behaviour. The RE inclusion LaAlO3 as heterogeneous nuclei of the primary M7C3 was medium effective, and could refine the M7C3 carbides. Besides, the wear resistance could be improved by adding La2O3 in the claddings.
Keywords:Fe-Cr-C cladding  rare earth oxide  carbides  microstructure
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