Tack and Green Strength of Blends of Bromobutyl and EPDM Rubbers. I. Unfilled Gum Blends

Polymer blends are gaining importance in recent years because they provide a compromise of properties. In this paper, tack and green strength of several blends of EPDM and bromobutyl rubbers (BIIR) have been studied over a wide range of temperaures, contact times and rates.

Tack increases with increase in contact time and with increase in contact temperature up to 47°C for a particular blend. At a much higher temperature the tack strength falls gradually. Green strength increases with increase in bromobutyl content and decreases with temperature. Tack index, a ratio of tack strength divided by the cohesive strength under the same geometry, decreases slowly with the test temperature. At a 50:50 ratio of BIIR:EPDM, the two rubbers form an interpenetrating network as observed under the phase contrast microscope.