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Micrometer‐Thick Graphene Oxide–Layered Double Hydroxide Nacre‐Inspired Coatings and Their Properties
Authors:You‐Xian Yan  Hong‐Bin Yao  Li‐Bo Mao  Abdullah M Asiri  Khalid A Alamry  Hadi M Marwani  Shu‐Hong Yu
Affiliation:1. Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, P. R. China;2. Center of Excellence for Advanced Materials Research, Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia
Abstract:Robust, functional, and flame retardant coatings are attractive in various fields such as building construction, food packaging, electronics encapsulation, and so on. Here, strong, colorful, and fire‐retardant micrometer‐thick hybrid coatings are reported, which can be constructed via an enhanced layer‐by‐layer assembly of graphene oxide (GO) nanosheets and layered double hydroxide (LDH) nanoplatelets. The fabricated GO–LDH hybrid coatings show uniform nacre‐like layered structures that endow them good mechanic properties with Young's modulus of ≈18 GPa and hardness of ≈0.68 GPa. In addition, the GO–LDH hybrid coatings exhibit nacre‐like iridescence and attractive flame retardancy as well due to their well‐defined 2D microstructures. This kind of nacre‐inspired GO–LDH hybrid thick coatings will be applied in various fields in future due to their high strength and multifunctionalities.
Keywords:flame retardants  iridescence  layer‐by‐layer assembly  mechanics  nacre
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