On‐Chip Production of Size‐Controllable Liquid Metal Microdroplets Using Acoustic Waves |
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Authors: | Shi‐Yang Tang Bugra Ayan Nitesh Nama Yusheng Bian James P. Lata Xiasheng Guo Tony Jun Huang |
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Affiliation: | 1. Department of Engineering Science and Mechanics, The Pennsylvania State University, University Park, PA, USA;2. Key Laboratory of Modern Acoustics (MOE), Department of Physics, Nanjing University, Nanjing, China |
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Abstract: | Micro‐ to nanosized droplets of liquid metals, such as eutectic gallium indium (EGaIn) and Galinstan, have been used for developing a variety of applications in flexible electronics, sensors, catalysts, and drug delivery systems. Currently used methods for producing micro‐ to nanosized droplets of such liquid metals possess one or several drawbacks, including the lack in ability to control the size of the produced droplets, mass produce droplets, produce smaller droplet sizes, and miniaturize the system. Here, a novel method is introduced using acoustic wave‐induced forces for on‐chip production of EGaIn liquid‐metal microdroplets with controllable size. The size distribution of liquid metal microdroplets is tuned by controlling the interfacial tension of the metal using either electrochemistry or electrocapillarity in the acoustic field. The developed platform is then used for heavy metal ion detection utilizing the produced liquid metal microdroplets as the working electrode. It is also demonstrated that a significant enhancement of the sensing performance is achieved by introducing acoustic streaming during the electrochemical experiments. The demonstrated technique can be used for developing liquid‐metal‐based systems for a wide range of applications. |
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Keywords: | acoustics EGaIn liquid metal electrochemistry heavy metal ion sensing microdroplets |
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