| 3,6-双胍基-1,2,4,5-四嗪及其盐的合成工艺改进 |
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| 引用本文： | 王伯周,廉鹏,刘愆,张海昊,王锡杰,白娟.3,6-双胍基-1,2,4,5-四嗪及其盐的合成工艺改进[J].含能材料,2006,14(5):352-354. |
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| 作者姓名： | 王伯周 廉鹏 刘愆 张海昊 王锡杰 白娟 |
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| 作者单位： | 西安近代化学研究所,陕西,西安,710065;西安近代化学研究所,陕西,西安,710065;西安近代化学研究所,陕西,西安,710065;西安近代化学研究所,陕西,西安,710065;西安近代化学研究所,陕西,西安,710065;西安近代化学研究所,陕西,西安,710065 |
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| 摘 要： | 以三氨基胍硝酸盐、戊二酮为起始原料,经缩合、氧化、取代、盐化等反应合成了3,6-双胍基-1,2,4,5-四嗪(DGTZ)及其高氯酸、硝酸、NTO盐,并采用红外光谱、核磁、DSC等分析手段确定它们的结构;对关键步骤氧化反应进行了改进,发现以亚硝酸钠/乙酸氧化新法,原材料易得,操作简便,收率较高,具有工业扩试前景。
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| 关 键 词： | 有机化学 合成 3 6-双胍基-1 2 4 5-四嗪 改进 |
| 文章编号： | 1006-9941（2006）05-0352-03 |
| 收稿时间： | 2006-03-27 |
| 修稿时间： | 2006-06-06 |
Synthesis Improvement of 3,6-Diguanidino-1,2,4,5-tetrazine and Its Salts |
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| WANG Bo-zhou,LIAN Peng,LIU Qian,ZHANG Hai-hao,WANG Xi-jie and BAI Juan.Synthesis Improvement of 3,6-Diguanidino-1,2,4,5-tetrazine and Its Salts[J].Chinese Journal of Energetic Materials,2006,14(5):352-354. |
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| Authors: | WANG Bo-zhou LIAN Peng LIU Qian ZHANG Hai-hao WANG Xi-jie and BAI Juan |
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| Abstract: | The synthesis of 3,6-diguandine-1,2,4,5-tetrazine(BDT) and its salts were described from triaminoguanidine nitrate and 2,4-pentanedione after condensation,oxidation and neutralization.Their structures were confirmed by IR,HMR,DSC.Taking CH_3COOH-NaNO_2 as oxidizer,CH_3COOH as reactive medium,BDT was obtained with the yield of 85% at room temperature.This improvement reduces the cost of synthesis,raises the yield,facilitates experimental operation. |
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| Keywords: | organic chemistry synthesis 3 6-diguandine-1 2 4 5-tetrazine(BDT) improvement |
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