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Study of Reactions Induced by Mechanical Milling in ZnO-α-Fe_2O_3 System
引用本文:汪礼敏,毛昌辉,杜军,刘落红,苏兰英,夏志华.Study of Reactions Induced by Mechanical Milling in ZnO-α-Fe_2O_3 System[J].稀有金属(英文版),2000,19(1).
作者姓名:汪礼敏  毛昌辉  杜军  刘落红  苏兰英  夏志华
作者单位:Wang Limin,Mao Changhui,Du Jun,Liu Luohong,Su Lanying and Xia Zhihua Department of Powder Metallurgy and Special Materials,General Research Institute for Nonferrous Metals,Beijing 100088,China
基金项目:ThisworkwasfinanciallysupportedbytheFoundationofAdvancedTechnologyoftheGeneralCompanyofNonferrousMetalsofChina.
摘    要:1 IntroductionChemicalreactionamongmetalsandmetalswithceramicsunderhigh energymechanicalmilling (MM)havebeenwide lystudied1~ 3] .Untilnow ,solidreactionsbetweenmetaloxidesunderMMhavebeenhardlystudied .ZnFe2 O4isakindofspinelferrite ,whichisgenerallysynthe sized…


Study of Reactions Induced by Mechanical Milling in ZnO-α-Fe2O3 System
Wang Limin,Mao Changhui,Du Jun,Liu Luohong,Su Lanying,Xia Zhihua.Study of Reactions Induced by Mechanical Milling in ZnO-α-Fe2O3 System[J].Rare Metals,2000,19(1).
Authors:Wang Limin  Mao Changhui  Du Jun  Liu Luohong  Su Lanying  Xia Zhihua
Abstract:Spinel ferrite ZnFe2O4 powders were synthesized directly from ZnO and α-Fe2O3 mixtures by high-energy mechanical milling. X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) were used to investigate the chemical reaction processing at different milling time. It has been found that the solid reactions between metal oxides are characterized by stages. Once the solid chemical-synthesized reaction is initialized, it proceeds quickly and can be completed in very short time. Grain sizes of ZnFe2O4 are less than 10 nm.
Keywords:High  energy mechanical milling  Nanometer material  Ferrite
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