Modulation of electrical properties in single-walled carbon nanotube/conducting polymer composites |
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Authors: | E. Tamburri S. Orlanducci M.L. Terranova F. Valentini A. Curulli D. Passeri M. Rossi |
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Affiliation: | a Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata”, Via della Ricerca Scientifica, 00133 Roma, Italy b MINASlab, Università di Roma “Tor Vergata”, Via della Ricerca Scientifica, 00133 Roma, Italy c CNR ISMN Istituto per lo Studio dei Materiali Nanostrutturati Sezione Roma 2, Via del Castro Laurenziano 7, 00161 Roma, Italy d Dipartimento di Ingegneria Elettronica and INFM, Università di Roma “Tor Vergata”, Via del Politecnico 1, 00133 Roma, Italy e Dipartimento di Energetica, Università di Roma “La Sapienza”, Via A. Scarpa 14, 00161 Roma, Italy |
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Abstract: | The preparation and electrical characterization of a new class of composite layers formed by dispersing single-walled carbon nanotubes (SWNT) in 1,8-diaminonaphthalene polymer, the poly(1,8-DAN), are described.The material was grown on the surface of Pt plates by electropolymerization of 1,8-diaminonaphthalene (1,8-DAN) monomer in the presence of nanotubes. This synthesis method allows the simultaneous deposition of both the host polymer matrix and the filler nanotubes. A series of composite films were prepared using untreated nanotubes as well as nanotubes treated with KOH, HNO3 and HNO3/H2SO4 solutions. The structural features of the nanotubes and of the films produced have been investigated using Raman spectroscopy. Insight into the nature of nanotube dispersion and nanotube-polymer association was gained by AFM and STM analysis and by FE-SEM inspection after removing the outermost portion of composite films.The charge transport in composite films is found to be strongly enhanced by the nanotube insertion. Depending on the SWNTs processing, currents up to 30 mA, higher by a factor of about 140 than those of the pure poly(1,8-DAN) films, were measured with an applied voltage of 250 mV. |
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Keywords: | Carbon nanotubes Chemical treatment, Electrochemical treatment Raman spectroscopy Electrical properties |
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