Unusually tight aggregation in detonation nanodiamond: Identification and disintegration |
| |
Authors: | A Krüger F Kataoka M Ozawa T Fujino AE Aleksenskii E ōsawa |
| |
Affiliation: | a Institut für Organische Chemie, Universität Kiel, Otto-Hahn-Platz 3, 24098 Kiel, Germany b Department of Knowledge Based Information Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580, Japan c NanoCarbon Research Institute, 304 Toudai Venture Plaza, 5-4-19 Kashiwa-no-Ha, Kashiwa, Chiba 277-0882, Japan d Products Development Centre, Futaba Corporation, 1080 Yabutsuka, Chosei-mura, Chosei-gun, Chiba 299-4395, Japan e Department of Integrated Biosciences, The University of Tokyo, Bunkyo-ku, Tokyo 113-8656, Japan f Ioffe Physico-Technical Institute, 26 Polytechnicheskaya, St. Petersburg 194021, Russia |
| |
Abstract: | A remarkable observation that detonation of oxygen-deficient explosives in an inert medium produces ultra-fine diamond particles having diameters of 4-5 nm was made four decades ago, but this novel form of diamond has never been isolated in pure form thereafter. The reason for the difficulty was that the core aggregates having a diameter range of 100-200 nm are extremely tight and could not be broken up by any known method of de-aggregation. After a number of futile attempts, we were able to obtain primary particles by using the recently emerging technique of stirred-media milling with micron-sized ceramic beads. The milled aqueous slurry of nanodiamond gave a stable, thick and dark-coloured colloidal solution. After light sonication, dynamic light scattering measurements gave a sharp distribution in the single-digit nano-range, and HRTEM indicated separate particles having diameters of 4-5 nm, which agreed with the X-ray value of 4.4 nm for the primary particles. A model is presented for the core aggregates, which resembles the well-known grape-shaped ‘aggregate structure’ of the hardest type of carbon black. |
| |
Keywords: | Diamond Modelling Electron microscopy X-ray diffraction Particle size |
本文献已被 ScienceDirect 等数据库收录! |
|