Solid-state wetting transitions at grain boundaries |
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Authors: | Paul Wynblatt Dominique Chatain |
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Affiliation: | aDepartment of Materials Science and Engineering, Carnegie Mellon University, Pittsburgh, PA 15213, USA;bCRMCN-CNRS, Campus de Luminy, 13288 Marseille cedex 9, France |
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Abstract: | A previously developed model of the dependence of grain boundary (GB) segregation on GB character has been exercised to investigate solid-state wetting transitions at GBs, and their anisotropy. In the case of binary systems displaying a solid-state miscibility gap, it is shown that the wetting transition temperature for precipitates at a GB is anisotropic, and is inversely related to GB energy. The model also allows calculation of prewetting transitions and associated excursions in adsorption off phase coexistence. These transitions are first order below a prewetting critical point (TPWC), and higher order at temperatures above TPWC. Investigation of the prewetting behavior provides the means for construction of the two-dimensional phase diagram of a GB. |
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Keywords: | Grain boundary adsorption Wetting transitions Prewetting transitions Grain boundary phase diagrams |
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