| 共缩聚反应中链段序列长度调控的分子模拟研究 |
| |
| 引用本文： | 张怀哲,刘静,马禹,余木火. 共缩聚反应中链段序列长度调控的分子模拟研究[J]. 当代化工, 2016, 0(4): 724-726. DOI: 10.3969/j.issn.1671-0460.2016.04.020 |
| |
| 作者姓名： | 张怀哲 刘静 马禹 余木火 |
| |
| 作者单位： | 东华大学,上海,201620 |
| |
| 基金项目： | 国家自然科学基金,项目号:21204011 |
| |
| 摘 要： | 利用分子模拟研究了共缩聚反应得到的高分子链上的嵌段长度分布。通过控制参加反应的两种组分的浓度比和共聚单体的反应活性,可得到与理论值差别很大的序列分布。有助于合成嵌段长度可控的共聚高分子。
|
| 关 键 词： | 分子模拟 共缩聚 嵌段长度 |
Simulation Study on Block Length Distribution Control in Cocondensation Polymerization |
| |
| ZHANG Huai-zhe;LIU Jing;MA Yu;YU Mu-huo. Simulation Study on Block Length Distribution Control in Cocondensation Polymerization[J]. Contemporary Chemical Industry, 2016, 0(4): 724-726. DOI: 10.3969/j.issn.1671-0460.2016.04.020 |
| |
| Authors: | ZHANG Huai-zhe LIU Jing MA Yu YU Mu-huo |
| |
| Affiliation: | ZHANG Huai-zhe;LIU Jing;MA Yu;YU Mu-huo;Donghua University; |
| |
| Abstract: | In this study, molecular simulation was employed to study the block length distribution along polymer chain obtained by cocondensation polymerization. It’s found that the distribution exhibits a significant deviation from the theoretical predictions, particularly for two components with different concentration and reactivity. This research is helpful for synthesis of copolymer with controlled block length. |
| |
| Keywords: | Molecular simulation Cocondensation polymerization Block length distribution |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
