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Influence of alloying on the free energy of austenitic grain boundaries in steel
Authors:B. B. Vynokur
Abstract:We compute the conditional energy σ, of austenitic grain boundaries and analyze changes in boundary energy at elevated temperatures for low-carbon, chrome-manganese and chrome-manganese-molybdcnum steels. It is established that σ, varies within the range 1.0–1.3 J/m2 and that, in almost all cases of alloying, the effect caused by a decrease in the surface energy of iron is so strong that even in the presence of chorophobic elements σ, decreases at elevated temperatures. For multicomponent steels, we analyze variations of the temperature coefficients of boundary energy. Philadelphia, United States of America. Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 32, No. 4, pp. 63–68, July–August, 1996
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