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三维有序介孔结构氧化钼制备及催化性能
引用本文:杜玉成,郑广伟,孟琪,王利平,范海光,戴洪兴.三维有序介孔结构氧化钼制备及催化性能[J].无机材料学报,2014,29(2):124-130.
作者姓名:杜玉成  郑广伟  孟琪  王利平  范海光  戴洪兴
作者单位:(北京工业大学 新型功能材料教育部重点实验室, 北京 100124)
摘    要:以三维有序介孔分子筛KIT-6为模板剂制备碳模板, 七钼酸铵为钼源, 采用超声辅助下的真空浸渍法, 合成了三维(3D)有序介孔、蠕虫状介孔MoO3。采用TEM、HRTEM、SAED、XRD、TG/DT、N2吸脱附等对材料物理性能进行了表征。采用H2-TPR、甲苯和一氧化碳完全氧化等对催化性能进行了评价。研究发现: 制备的三维有序介孔MoO3为正交相晶体结构, 比表面积194 m2/g; 在转化率分别为50%、90%、100%时, 甲苯的起燃温度分别为203℃、215℃、225℃; CO起燃温度分别为114℃、158℃、180℃。3D-MoO3优良的催化性能与高比表面和三维有序介孔架构密切相关。

关 键 词:模板剂  三维有序介孔  氧化钼  甲苯燃烧  一氧化碳氧化  
收稿时间:2013-04-24
修稿时间:2013-08-27

Fabrication and Excellent Catalytic Performance of Three-dimensional Ordered Mesoporous Molybdenum Oxides
DU Yu-Cheng,ZHENG Guang-Wei,MENG Qi,WANG Li-Ping,FAN Hai-Guang,DAI Hong-Xing.Fabrication and Excellent Catalytic Performance of Three-dimensional Ordered Mesoporous Molybdenum Oxides[J].Journal of Inorganic Materials,2014,29(2):124-130.
Authors:DU Yu-Cheng  ZHENG Guang-Wei  MENG Qi  WANG Li-Ping  FAN Hai-Guang  DAI Hong-Xing
Affiliation:(Key Lab of Advanced Functional Materials, Ministry of Education, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China)
Abstract:Three-dimensional (3D) ordered and wormhole-like MoO3 mesoporous structures were synthesized based on ultrasound-assisted vacuum impregnation method. Carbon template was used in the synthesis process, which was prepared by using mesoporous molecular sieve KIT-6. Hexaammonium molybdate acted as molybdenum source. The as-prepared MoO3 samples were characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), thermogravimetric analysis/differenctial scanning calorimetry (TG/DSC), and N2 adsorption-desorption measurement. The catalytic performance of MoO3 mesoporous structure was evaluated by hydrogen temperature-programmed reduction (H2-TPR), and complete oxidation of toluene and carbon monoxide (CO). It was found that the initiation temperatures of toluene were 203℃, 215℃ and 225℃, respectively, and the initiation temperatures of CO were 114℃, 158℃ and 180℃, respectively, with their conversion rates of 50%, 90% and 100%, respectively. The well catalytic performance was attributed to 3D ordered mesoporous structure and high surface area of as-obtained MoO3 materials.
Keywords:template reagent  three-dimensional ordered mesopore  molybdenum oxide  toluene combustion  CO combustion  
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