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硫酸铵-丁二酮肟-乙醇体系萃取分离钴的研究
引用本文:李全民,申义阳,张青芬,刘奇.硫酸铵-丁二酮肟-乙醇体系萃取分离钴的研究[J].冶金分析,1999,19(4):1-1.
作者姓名:李全民  申义阳  张青芬  刘奇
作者单位:河南师范大学化学系!新乡,453002,河南师范大学化学系!新乡,453002,河南师范大学化学系!新乡,453002,河南师范大学化学系!新乡,453002
基金项目:河南省科委、省教委自然科学基金
摘    要:研究了硫酸铵-丁二酮肟-乙醇体系萃取Co(Ⅱ)的行为及乙醇与水溶液分相条件.试验表明,作为萃取溶剂的乙醇,能萃取带电络合物,当溶液pH>5时,能使Co(Ⅱ)与Ni(Ⅱ),Fe(Ⅲ)分别在乙醇相、浮选相及水相中实现同一体系中三相分离.

关 键 词:乙醇  萃取分离    

Study on Extraction Separation of Cobalt with (NH4)2SO4 -Biacetyl dioxime-ethanol System
Li Quanmin,Shen Yiyang,Zhang Qingfen,Liu Qi.Study on Extraction Separation of Cobalt with (NH4)2SO4 -Biacetyl dioxime-ethanol System[J].Metallurgical Analysis,1999,19(4):1-1.
Authors:Li Quanmin  Shen Yiyang  Zhang Qingfen  Liu Qi
Abstract:The extraction behaviour of (NH4)2SO4-biacetyl dioxine-ethanol system was studied and proper conditions were selected. It shows that the complex of Co2 and biacetyl dioxime can be extracted into the ethanol phase, the precipitate of Ni2 and biacetyl doixime floats between the two phases while the Fe3 is left in the aqueous solvent at PH>5. It is concluded that Co2 can be separated completely from Fe3 and Ni2 in the system.
Keywords:Cobalt  Extraction separation  Ethanol
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