| 硝酸酯类含能黏合剂绿色合成研究进展 |
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| 引用本文： | 王庆法,米镇涛,张香文,王莅.硝酸酯类含能黏合剂绿色合成研究进展[J].化学推进剂与高分子材料,2008,6(2):11-15. |
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| 作者姓名： | 王庆法 米镇涛 张香文 王莅 |
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| 作者单位： | 天津大学化工学院,天津,300072 |
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| 摘 要： | 对3种具有发展潜力的硝酸酯类含能黏合剂聚(3-甲基硝酸酯-3-甲基环氧丁烷)(Poly-NIMMO)、聚缩水甘油硝酸酯(PolyGLYN)和硝化端羟基聚丁二烯(NHTPB)的绿色合成工艺和性质进行了简要评述,分析了这些黏合剂的发展前景。并采用以五氧化二氮为硝化剂的绿色合成路线制备得到NHTPB黏合剂,考察了不同官能团对其热稳定性和玻璃化转变温度的影响规律。
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| 关 键 词： | 硝酸酯 含能黏合剂 NHTPB 绿色合成 |
| 文章编号： | 1672-2191(2008)02-0011-05 |
| 修稿时间： | 2007年11月14 |
Research Progress in Green Synthesis of Energetic Binders of Nitrate Esters |
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| WANG Qing-fa,MI Zhen-tao,ZHANG Xiang-wen,WANG Li.Research Progress in Green Synthesis of Energetic Binders of Nitrate Esters[J].Chemical Propellants & Polymeric Materials,2008,6(2):11-15. |
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| Authors: | WANG Qing-fa MI Zhen-tao ZHANG Xiang-wen WANG Li |
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| Abstract: | The green synthesis processes and properties of three nitrate ester binders with development potentiality including poly (3-nitratomethyl-3-methyloxetane)(polyNIMMO), polyglycidyl nitrate(polyGLYN) and nitrated hydroxy-terminated polybutadiene (NHTPB) are reviewed briefly. Their development prospect is analysed. The NHTPB binder was synthesized by a green route using dinitrogen pentoxide as nitrating agent. The effects of different functional groups on the thermal stability and glass transition temperature of NHTPB were investigated. |
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| Keywords: | nitrate ester energetic binder NHTPB green synthesis |
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