Nano-alumina coated with sodium dodecyl sulfate and modified with 4-(2-Pyridylazo) resorcinol for extraction of heavy metals in different matrixes |
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Affiliation: | 1. Department of Polymer Chemistry, National Center for Radiation Research and Technology, Nasr City, Cairo, Egypt;2. Department of Chemistry, Faculty of Science, Suez Canal University, Ismailia, Egypt;1. Department of Naval Architecture and Ocean Engineering, Pusan National University, 63 Jangjeon-dong, Geumjeong-gu, Busan 609-735, South Korea;2. Department of Environmental Engineering, Kyungpook National University, 80 University Road, Bukgu, Daegu 702-701, South Korea;1. Engineering School of Lorena, University of São Paulo, P.O. Box 116, 12602-810 Lorena, SP, Brazil;2. Laboratory of Biocatalysis, Federal University of São João del-Rei, 35701-970 Sete Lagoas, MG, Brazil |
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Abstract: | A green, novel and efficient solid phase extraction method based on the use of nano-alumina (nano-Al2O3) coated with sodium dodecyl sulfate (SDS) and modified with 4-(2-Pyridylazo) resorcinol (PAR) as a new adsorbent was developed for separation and preconcentration of trace amounts of Ni, Pb, Cu and Zn ions prior to determination by inductively coupled plasma-optical emission spectrometry (ICP-OES). Under the optimum conditions (eluent: HNO3, 4.0 mL, 3.0 mol L−1; adsorbent: 0.8 g of nano-Al2O3, 40 mg of SDS, 8.6 mg of PAR; and sample: pH 6, flow rate 2.0 mL min−1), adsorption capacity of nano-Al2O3-SDS-PAR, enrichment factors and limits of detection for the analytes were 8.7–12.9 mg g−1, 125–250, and 0.12–0.71 μg L−1, respectively. The proposed method presented excellent repeatability with relative standard deviations less than 1.6% (n = 10), and calculated calibration curves gave good level of linearity with correlation coefficient values between 0.989 and 0.999. Finally, the feasibility of the method was evaluated by extraction and determination of Ni, Pb, Cu and Zn ions in rice seed, apple juice, coriander, lettuce and tap water samples. |
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Keywords: | Nano-alumina 4-(2-Pyridylazo) resorcinol Sodium dodecyl sulfate Inductively coupled plasma-optical emission spectrometry Solid phase extraction |
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