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Low-temperature catalytic conversion of lignite: 3. Tar reforming using the supported potassium carbonate
Affiliation:1. State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, China;2. China-EU Institute for Clean and Renewable Energy, Huazhong University of Science and Technology, Wuhan 430074, China;3. Fuels and Energy Technology Institute, Curtin University of Technology, GPO Box U1987, Perth, Western Australia 6845, Australia
Abstract:Alumina-supported K2CO3–LaMn0.8Cu0.2O3 was investigated for the catalytic conversion of tar, produced from lignite, into syngas under inert and steam-reforming conditions. A double-bubble fluidized bed reactor system, equipped with a micro gas chromatograph and a collecting system to analyze permanent gases and condensable species, was developed to screen the catalytic conversion of tar components below 700 °C. The redox properties of catalysts, estimated by hydrogen temperature programmed reduction analyses, were correlated with their catalytic performance in tar conversion. The synthesized catalyst effectively converted tars into hydrogen-rich syngas and also improved tar reforming by inhibiting coke deposition.
Keywords:Catalytic steam coal gasification  Tar Reforming  Perovskite
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